研究论文
Flexible Piezoelectric Nanogenerators from BaTiO₃/PVDF Nanocomposite Films for Wearable Energy Harvesting
摘要
Flexible piezoelectric nanogenerators (PENGs) based on BaTiO₃ nanoparticle-reinforced poly(vinylidene fluoride) (PVDF) composite films are developed for harvesting biomechanical energy from human motion. The nanocomposite films with 20 wt% BaTiO₃ content and β-phase PVDF fraction of 82% achieve an open-circuit voltage of 68 V, short-circuit current of 12.5 μA, and peak power density of 285 μW/cm² under cyclic compressive loading at 5 Hz — representing a 4.2× improvement over pristine PVDF films. The enhanced performance originates from synergistic polarization of ferroelectric BaTiO₃ nanoparticles and strain-induced β-phase crystallization of the PVDF matrix. A wearable wristband prototype successfully powers a commercial temperature-humidity sensor and Bluetooth Low Energy transmitter from finger-tapping motions, demonstrating practical viability for self-powered wearable electronics.